Plants contain a molecule called chlorophyll, which is used in photosynthesis to make food for the plant. chlorophyul is also green and givers plants their green colour. In the winter, however, there is less sun and so most plants have evolved to live off the nutrients they have stored up during the summer. So, in the autumn, the chlorophyll begins to break down, so that the yellows and reds in the plant are visible, which is why you see a change in colour. If you want a more detailed explanation, http://www.sciencemadesimple.com/leaves.html explains it really well :).
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